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Melting chocolate to use as a baking ingredient for candy work or decoration requires gentle heat. Chocolate that is overheated may scorch, lose flavor and turn coarse and grainy. Stir melting chocolate after it has begun to liquefy. Because of the sensitivity of milk solids to heat, milk and white chocolates should be stirred almost constantly while dark chocolate need only be stirred frequently during melting.
Here are two good methods for melting chocolate so that it is smooth and glossy.
Place coarsely chopped chocolate in a microwave-safe container and microwave at MEDIUM (50 percent power) for 1 1/2 to 4 minutes, until the chocolate turns shiny. Remove the container from the microwave and stir the chocolate until completely melted. Stir milk and white chocolates after about 1 1/2 minutes. Because of their milk proteins, they need to be stirred sooner than dark chocolate. (If overheated, these chocolates may become grainy.)
Place coarsely chopped chocolate in the top of a double boiler over hot, not simmering, water. Melt the chocolate, stirring until smooth. Remove the top part of the double boiler from the bottom.
Using a microwave oven in combination with the time-honored professional method of tempering chocolate on a smooth, hard work surface (preferably marble) is quickly done in 10 to 30 minutes, depending on the amount of chocolate being tempered. Although some manufacturers suggest you melt chocolate with the microwave oven set on HIGH (100 percent) power, it is a good idea to reduce this to MEDIUM (50 percent) power for even melting and to avoid overheating. Because milk and white chocolates contain milk proteins, they need to be removed from the microwave and stirred sooner than dark chocolate. If overheated, milk and white chocolates can become grainy.
Temper chocolate in a clean, dry microwave-safe glass bowl. Use a dry, rubber spatula to stir the melted chocolate. The slightest amount of moisture will cause the chocolate to seize.
Use an accurate easy-to-read thermometer when tempering or making hand-made chocolates. We recommend a digital pocket thermometer or an instant read dial thermometer with l-degree increments. Do not use a candy (deep fat frying) thermometer because the temperature gauge does not register low enough.
For an accurate temperature reading, the thermometer must be immersed in at least 2 inches of melted chocolate. If the chocolate is not deep enough, insert the stem of the thermometer at an angle. Do not let the tip of the thermometer touch the bottom or sides of the bowl because this can give a false reading. Always stir the chocolate thoroughly for at least 1 minute before reading the thermometer. The temperature of the chocolate will continue to rise even after it has been removed from the microwave.
Once the chocolate has been tempered, set the bowl on a heating pad (such as the type used for backaches). First wrap the heating pad with plastic to protect it from dripping chocolate. This is a simple and nearly foolproof way to maintain the temperature of the tempered chocolate. As you work, stir the chocolate frequently and turn the control dial on and off to control the temperature of the chocolate. You must be diligent in this; it is very easy for the tempered chocolate to overheat and to go out of temper, even when warmed gently by a heating pad.
Chocolatier Magazine's Chocolate Key